4.8 Article

Continuous Visible-Light Photoflow Approach for a Manganese-Catalyzed (Het)Arene C-H Arylation

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 33, Pages 10625-10629

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805644

Keywords

C-H arylations; continuous photoflow reactions; manganese; photocatalysis; visible light

Funding

  1. Alexander von Humboldt Foundation
  2. DFG (Gottfried-Wilhelm-Leibniz prize)

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Manganese photocatalysts enabled versatile room-temperature C-H arylation reactions by means of continuous visible-light photoflow, thus allowing for efficient C-H arylations in 30 minutes with ample scope. The robustness of the manganese-catalyzed photoflow strategy was shown by visible light-induced gram-scale synthesis, clearly outperforming the batch performance.

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