Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 21, Pages 6100-6103Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201802079
Keywords
borates; iodides; nonlinear optical materials; Pb2BO3I; second-harmonic generation
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Funding
- NSF [DMR-1454688, DMR-1503573]
- Welch Foundation [E-1457]
- Division Of Materials Research [1503573, 1454688] Funding Source: National Science Foundation
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Borate halides are an ideal materials class from which to design high-performance nonlinear optical (NLO) materials. Currently, borate fluorides, chlorides, and bromides are extensively investigated while borate iodide materials discovery remains rare because of the perceived synthetic challenges. We report a new borate iodide, Pb2BO3I, synthesized by a straightforward hydrothermal method. The Pb2BO3I chemical formula conceals that the compound exhibits a structure similar to the well-established KBe2BO3F2 (KBBF), which we show supports the highest second-harmonic generation (SHG) at 1064 nm in the KBBF family, 10 x KH2PO4 (KDP), arising from the inclusion of Pb2+ and I- and the crystal chemistry. Our work shows that KBBF-related compounds can be synthesized incorporating iodide and exhibit superior NLO responses.
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