Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 18, Pages 5016-5019Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201800884
Keywords
coordination polymers; electron diffraction; iron; metal-organic frameworks; phosphinic acids
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Funding
- Czech Science Foundation [16-02098S]
- project ASTRA of the Operation program Prague Competitiveness [CZ.2.16/3.1.00/24510]
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Metal-organic frameworks (MOFs) are a chemically and topologically diverse family of materials composed of inorganic nodes and organic linkers bound together by coordination bonds. Presented here are two significant innovations in this field. The first is the use of a new coordination group, phenylene-1,4-bis(methylphosphinic acid) (PBPA), a phosphinic acid analogue of the commonly used terephtalic acid. Use of this new linker group leads to the formation of a hydrothermally stable and permanently porous MOF structure. The second innovation is the application of electron-diffraction tomography, coupled with dynamic refinement of the EDT data, to the elucidation of the structure of the new material, including the localization of hydrogen atoms.
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