Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 32, Pages 10236-10240Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201806093
Keywords
chiroptics; metal-ligand charge transfer; molybdenum oxide; nanoparticles; surface plasmon
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Funding
- National Natural Science Foundation of China [11574130, 11404161]
- Shenzhen Science and Technology Innovation Committee [KQJSCX20170726145748464, JCYJ20150930160634263, JCYJ20170302142433007, KQTD2015071710313656]
- University of Macau [MYRG 2018-00142, FDCT 199/2017/A3]
- National 1000 plan for Young Talents
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Understanding the interactions between a semiconducting nanocrystal surface and chiral anchoring molecules could resolve the mechanism of chirality induction in nanoscale and facilitate the rational design of chiral semiconducting materials for chiroptics. Now, chiral molybdenum oxide nanoparticles are presented in which chirality is transferred via a bio-to-nano approach. With facile control of the amount of chiral cysteine molecules under redox treatment, circular dichroism (CD) signals are generated in the plasmon region and metal-ligand charge-transfer band. The obtained enhanced CD signals with tunable lineshapes illustrate the possibility of using chiral molybdenum oxide nanoparticles as potentials for chiral semiconductor nanosensors, optoelectronics, and photocatalysts.
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