Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 35, Pages 11233-11237Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805063
Keywords
graphene; nanostructures; porphyrinoids; self-assembly; supramolecular chemistry
Categories
Funding
- Max Planck Society
- European Union [696656]
- Marie-Curie ITN project iSwitch (GA) [642196]
- FWO [EOS 30489208]
- internal funds-KU Leuven
Ask authors/readers for more resources
Two unprecedented porphyrin fused nanographene molecules, 1 and 2, have been synthesized by the Scholl reaction from tailor-made precursors based on benzo[m]tetraphene-substituted porphyrins. The chemical structures were validated by a combination of high-resolution matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (HR MALDI-TOF MS), IR and Raman spectroscopy, and scanning tunnelling microscopy (STM). The UV-vis-near infrared absorption spectroscopy of 1 and 2 demonstrated broad and largely red-shifted absorption spectra extending up to 1000 and 1400nm, respectively, marking the significant extension of the pi-conjugated systems.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available