Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 35, Pages 11228-11232Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201803244
Keywords
adsorption selectivity; core-shell crystals; porous cage crystals; surface hydrophobicity
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Funding
- ExxonMobil Research and Engineering Company
- European Union [321156]
- Engineering and Physical Sciences Research Council (EPSRC) [EP/N004884/1]
- EPSRC [EP/N004884/1] Funding Source: UKRI
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The first examples of core-shell porous molecular crystals are described. The physical properties of the core-shell crystals, such as surface hydrophobicity, CO2/CH4 selectivity, are controlled by the chemical composition of the shell. This shows that porous core-shell molecular crystals can exhibit synergistic properties that out-perform materials built from the individual, constituent molecules.
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