Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 18, Pages 5139-5142Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201801305
Keywords
alkenes; C-C bond cleavage; ortho-alkylation; photocatalysis; pyridine N-oxides
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Funding
- MEXT [JP15H05756, JP16K05694]
- JST ACT-C Grant, Japan [JPMJCR12Z9]
- JSPS
- Grants-in-Aid for Scientific Research [15H05756, 16K05694] Funding Source: KAKEN
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A photocatalyzed reaction of pyridine N-oxides with alkenes gives ortho-alkylated pyridines with cleavage of the carbon-carbon double bond. Benzyl and secondary alkyl groups are incorporated at the ortho position of pyridines in one pot.
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