Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 57, Issue 21, Pages 6136-6140Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201800973
Keywords
[2+2+2] cycloaddition; alkynes; heterogeneous catalysis; nanoparticles; Pd-Au alloys
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Funding
- Program for Elements Strategy Initiative for Catalysts & Batteries (ESICB)
- MEXT of Japan [17H03459, 17H06443]
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A Pd-Au alloy efficiently catalyzed the [2+2+2] cycloaddition of substituted alkynes. Whereas monometallic Pd and Au catalysts were totally ineffective, Pd-Au alloy nanoparticle catalysts with a low Pd/Au molar ratio showed high activity to give the corresponding polysubstituted arenes in high yields. A variety of substituted alkynes participated in various modes of cycloaddition under Pd-Au alloy catalysis. The Pd-Au alloy catalysts exhibited high air tolerance and reusability.
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