Journal
ANALYTICA CHIMICA ACTA
Volume 1015, Issue -, Pages 27-34Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2018.02.035
Keywords
Conjugated microporous polymers; Solid-phase microextraction; Phenols; Gas chromatographye-tandem mass spectrometry
Categories
Funding
- National Natural Science Foundation of China [21777089, 21477068]
- Key Research and Development Program of Shandong Province [2017GSF17107]
- Shandong Province Taishan Scholar Program
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The high performance separation and pre-concentration of polar phenols from aqueous matrices is difficult because of the strong interactions between phenols and water molecules. Conjugated micro-porous polymers (CMPs) are a kind of novel porous organic materials. Polyphenylene core-conjugated microporous polymers (PPc-CMPs) were used as a novel coating material in the solid-phase micro-extraction of polar phenols in water samples for the first time. The novel PPc-CMPs fibers exhibited good thermal stability (>450 degrees C), high enrichment factors (519-2372), low limits of detection (0.02-0.05 ng L-1), wide linearity (0.1-1000 ng L-1), and good repeatability (2.5%-8.1%) for polar phenols. The new coating was successfully used in the analysis of phenols in real environmental water samples. PPc-CMPs as a polar solid-phase microextraction coating material was excellent for the rapid and sensitive analysis of phenols at trace levels in the environment. (C) 2018 Elsevier B.V. All rights reserved.
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