Journal
CHEMCATCHEM
Volume 8, Issue 13, Pages 2217-2221Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201600419
Keywords
carbon dioxide hydrogenation; catalyst shaping; covalent triazine frameworks; formic acid
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Funding
- European Union [309701]
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A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50-90 degrees C) and in the dehydrogenation of formic acid.
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