3.8 Article

Shortening and dispersion of single-walled carbon nanotubes upon interaction with mixed supramolecular compounds

Journal

BIO-ALGORITHMS AND MED-SYSTEMS
Volume 12, Issue 3, Pages 123-132

Publisher

WALTER DE GRUYTER GMBH
DOI: 10.1515/bams-2016-0015

Keywords

atomic force microscopy (AFM); Congo red (CR); doxorubicin (DOX); dynamic light scattering (DLS); Evans blue (EB); scanning electron microscopy (SEM); single-walled carbon nanotubes (SWNT); transmission electron microscopy (TEM)

Funding

  1. project Interdisciplinary PhD Studies Molecular Sciences for Medicine
  2. European Social Fund within the Human Capital Operational Programme
  3. Ministry of Science and Higher Education [K/DSC/001370]

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Congo red (CR) dye molecules self-associate in water solutions creating ribbon-like supramolecular structures that can bind various aromatic compounds by intercalation, forming mixed supramolecular systems. Mixed supramolecular systems, such as CR-doxorubicin and CR-Evans blue, interact with the surface of carbon nanotubes, leading to their stiffening and ultimately to their breaking and shortening. This work presents a simple method of obtaining short and straight carbon nanotubes with significantly better dispersion in aqueous solutions and consequently improved usability in biological systems.

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