Journal
ADVANCED MATERIALS
Volume 30, Issue 13, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201706747
Keywords
Fe@gamma-Fe2O3@ H-TiO2; hydrogenated TiO2; multimodal imaging; photothermal cancer therapy; solar-driven photocatalysis
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Funding
- National Natural Science Foundation of China [NSFC51672268, 51472233, 51332008, 51720105015, 51628201, 21521092]
- Key Research Program of Frontier Sciences, CAS [YZDY-SSW-JSC018]
- Projects for Science and Technology Development Plan of Jilin province [20170414003GH]
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Titanium dioxide (TiO2) has been widely investigated and used in many areas due to its high refractive index and ultraviolet light absorption, but the lack of absorption in the visible-near infrared (Vis-NIR) region limits its application. Herein, multifunctional Fe@gamma-Fe2O3@ H-TiO2 nanocomposites (NCs) with multilayer-structure are synthesized by one-step hydrogen reduction, which show remarkably improved magnetic and photoconversion effects as a promising generalists for photocatalysis, bioimaging, and photothermal therapy (PTT). Hydrogenation is used to turn white TiO2 in to hydrogenated TiO2 (H-TiO2), thus improving the absorption in the Vis-NIR region. Based on the excellent solar-driven photocatalytic activities of the H-TiO2 shell, the Fe@gamma-Fe2O3 magnetic core is introduced to make it convenient for separating and recovering the catalytic agents. More importantly, Fe@gamma-Fe2O3@ H-TiO2 NCs show enhanced photothermal conversion efficiency due to more circuit loops for electron transitions between H-TiO2 and gamma-Fe2O3, and the electronic structures of Fe@gamma-Fe2O3@ H-TiO2 NCs are calculated using the Vienna ab initio simulation package based on the density functional theory to account for the results. The reported core-shell NCs can serve as an NIR-responsive photothermal agent for magnetic-targeted photothermal therapy and as a multimodal imaging probe for cancer including infrared photothermal imaging, magnetic resonance imaging, and photoacoustic imaging.
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