4.8 Article

Abnormal Synergetic Effect of Organic and Halide Ions on the Stability and Optoelectronic Properties of a Mixed Perovskite via In Situ Characterizations

Journal

ADVANCED MATERIALS
Volume 30, Issue 28, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201801562

Keywords

decomposition mechanism; formamidinium-cesium mixed perovskite; in situ characterization; intrinsic stability; synergetic composition effect

Funding

  1. Research Grants Council of Hong Kong [AoE/P-03/08, T23-407/13-N, AoE/P-02/12, 14207515, 14204616, 15246816]
  2. CUHK Group Research Scheme
  3. Innovation and Technology Commission, Hong Kong SAR Government [ITS/088/17]
  4. National Natural Science Foundation of China [61229401, 11574119, 61674070]
  5. funding for Project of Strategic Importance by the Hong Kong Polytechnic University [1-ZE29]

Ask authors/readers for more resources

The mixed cation lead mixed halide perovskite (MLMP) Cs(x)FA(1-x)PbI(y)Br(3-y) is one of the most promising candidates for both single-junction and tandem solar cells due to its high efficiency and remarkable stability. However, the composition effect on thermal stability and photovoltaic performances has not yet been comprehensively investigated. Therefore, the interplay between composition, crystal structure, morphology, and optoelectronic properties under heat stress, is systematically elucidated here through a series of in situ characterizations. It is revealed for the first time that the FA(+) and Br- release synchronously at first even under mild annealing. This leads to a serious FA- and Br-deficiency issue, with only 88.3% of Br and 90.2% of FA retained after annealing at 100 degrees C, which significantly magnifies the hysteresis, phase segregation, and instability issues. Finally, a trace amount of FA(+) and Br- is introduced onto the post-annealed MLMP surface to compensate for the deficiency through vacancy filling. The degradation lifetime to 80% of the initial efficiency (t(80)) is improved from 504 to 1056 h and the hysteresis issue is also well resolved. This work highlights the importance of the synergetic composition effect of the organic cation and halide anion on stability and efficiency optimization for long-term applications.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available