4.8 Article

A Nonaqueous Potassium-Based Battery-Supercapacitor Hybrid Device

Journal

ADVANCED MATERIALS
Volume 30, Issue 20, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201800804

Keywords

batteries; battery-supercapacitor hybrid devices; nonaqueous batteries; potassium ion electrolytes; supercapacitors

Funding

  1. National Natural Science Foundation of China [51672078, 21473052]
  2. Hunan University State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body Independent Research Project [71675004]
  3. Hunan Youth Talents [2016RS3025]
  4. Foundation of State Key Laboratory of Coal Conversion [J17-18-903]

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A low cost nonaqueous potassium-based battery-supercapacitor hybrid device (BSH) is successfully established for the first time with soft carbon as the anode, commercialized activated carbon as the cathode, and potassium bis(fluoro-slufonyl)imide in dimethyl ether as the electrolyte. This BSH reconciles the advantages of potassium ion batteries and supercapacitors, achieving a high energy density of 120 W h kg(-1), a high power density of 599 W kg(-1), a long cycle life of 1500 cycles, and an ultrafast charge/slow discharge performance (energy density and power density are calculated based on the total mass of active materials in the anode and cathode). This work demonstrates a great potential of applying the nonaqueous BSH for low cost electric energy storage systems.

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