Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 28, Issue 11, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201705095
Keywords
conformation locking; high-performance solar cells; nonfullerene organic solar cells; steric hindrance
Categories
Funding
- National Natural Science Foundation of China [51573077]
- Open Project Program of State Key Laboratory of Organic-Inorganic Composites [oic-201701009]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- U.S. Office of Naval Research [N00014-15-1-2244]
- DOE, Office of Science
- DOE, Office of Basic Energy Sciences
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In this work, sidechain engineering on conjugated fused-ring acceptors for conformation locking is demonstrated as an effective molecular design strategy for high-performance nonfullerene organic solar cells (OSCs). A novel nonfullerene acceptor (ITC6-IC) is designed and developed by introducing long alkyl chains into the terminal electron-donating building blocks. ITC6-IC has achieved definite conformation with a planar structure and better solubility in common organic solvents. The weak electron-donating hexyl upshifts the lowest unoccupied molecular orbital level of ITC6-IC, resulting in a higher V-OC in comparison to the widely used ITIC. The OSCs based on PBDB-T:ITC6-IC reveal a promising power conversion efficiency of 11.61% and an expected high V-OC of 0.97 V. The weaker - stacking induced by steric hindrance affords ITC6-IC with enhanced compatibility with polymer donors. The blend film treated with suitable thermal annealing exhibits a fibril crystallization feature with a good bicontinuous network morphology. The results indicate that the molecular design approach of ITC6-IC can be inspirational for future development of nonfullerene acceptors for high efficiency OSCs.
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