Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 28, Issue 13, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201705847
Keywords
flexible solar cells; fullerene; polymer solar cells; self-doping; thickness-insensitive photovoltaics
Categories
Funding
- National Natural Science Foundation of China [51673138, 91633301]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Jiangsu Provincial Natural Science Foundation [BK20160059]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [16KJB430027]
- China Postdoctoral Science Foundation [2017M610347]
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To achieve high-performance large-area flexible polymer solar cells (PSCs), one of the challenges is to develop new interface materials that possess a thermal-annealing-free process and thickness-insensitive photovoltaic properties. Here, an n-type self-doping fullerene electrolyte, named PCBB-3N-3I, is developed as electron transporting layer (ETL) for the application in PSCs. PCBB-3N-3I ETL can be processed at room temperature, and shows excellent orthogonal solvent processability, substantially improved conductivity, and appropriate energy levels. PCBB-3N-3I ETL also functions as light-harvesting acceptor in a bilayer solar cell, contributing to the overall device performance. As a result, the PCBB-3N-3I ETL-based inverted PSCs with a PTB7-Th:PC71BM photoactive layer demonstrate an enhanced power conversion efficiency (PCE) of 10.62% for rigid and 10.04% for flexible devices. Moreover, the device avoids a thermal annealing process and the photovoltaic properties are insensitive to the thickness of PCBB-3N-3I ETL, yielding a PCE of 9.32% for the device with thick PCBB-3N-3I ETL (61 nm). To the best of one's knowledge, the above performance yields the highest efficiencies for the flexible PSCs and thick ETL-based PSCs reported so far. Importantly, the flexible PSCs with PCBB-3N-3I ETL also show robust bending durability that could pave the way for the future development of high-performance flexible solar cells.
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