Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 28, Issue 31, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201801734
Keywords
benzotriselenophene; heteroatom effect; hole transporting materials; perovskite; solar cells
Categories
Funding
- European Commission [H2020-ICT-2014-1, 643791]
- Swiss State Secretariat for Education, Research and Innovation (SERI)
- European Research Council [ERC-320441-Chirallcarbon]
- Spanish Ministry of Economy and Competitiveness MINECO [CTQ2014-52045-R, CTQ2015-71154-P, CTQ2015-71936-REDT, CTQ2016-81911-REDT, SEV-2016-0686, MDM-2015-0538]
- CAM [S2013/MIT-2841]
- Generalitat Valenciana [PROMETEO/2016/135, APOSTD/2017/081]
- European Feder funds [CTQ2015-71154-P]
- MINECO [IJCI-2015-26154]
- Qatar Environment and Energy Research Institute (QEERI), Hamad Bin Khalifa University (HBKU), Qatar Foundation Doha, Qatar
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Three new star-shaped hole-transporting materials (HTMs) incorporating benzotripyrrole, benzotrifuran, and benzotriselenophene central cores endowed with three-armed triphenylamine moieties (BTP-1, BTF-1, and BTSe-1, respectively) are designed, synthesized, and implemented in perovskite solar cells (PSCs). The impact that the heteroatom-containing central scaffold has on the electrochemical and photophysical properties, as well as on the photovoltaic performance, is systematically investigated and compared with their sulfur-rich analogue (BTT-3). The new HTMs exhibit suitable highest-occupied molecular orbitals (HOMO) levels regarding the valence band of the perovskite, which ensure efficient hole extraction at the perovskite/HTM interface. The molecular structures of BTF-1, BTT-3, and BTSe-1 are fully elucidated by single-crystal X-ray crystallography as toluene solvates. The optimized (FAPbI(3))(0.85)(MAPbBr(3))(0.15)-based perovskite solar cells employing the tailor-made, chalcogenide-based HTMs exhibit remarkable power conversion efficiencies up to 18.5%, which are comparable to the devices based on the benchmark spiro-OMeTAD. PSCs with BTP-1 exhibit a more limited power conversion efficiency of 15.5%, with noticeable hysteresis. This systematic study indicates that chalcogenide-based derivatives are promising HTM candidates to compete efficiently with spiro-OMeTAD.
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