Journal
ADVANCED ENGINEERING MATERIALS
Volume 20, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adem.201700782
Keywords
Bioinspired Composites; Ceramic-metal Composites; Electroless Plating; Multifunctional Composites; Fracture Toughness; Spark-Plasma Sintering (field-assisted sintering)
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Funding
- Air Force Office of Scientific Research [FA9550-14-1-0252]
- U.S. Army Research Laboratory [W911NF-15-2-0106]
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Hybrid composites of layered brittle-ductile constituents assembled in a brick-and-mortar architecture are promising for applications requiring high strength and toughness. Mostly, polymer mortars have been considered as the ductile layer in brick-and-mortar composites. However, low stiffness of polymers does not efficiently transfer the shear between hard ceramic bricks. Theoretical models point to metals as a more efficient mortar layer. However, infiltration of metals into ceramic scaffold is non-trivial, given the low wetting between metals and ceramics. The authors report on an alternative approach to fabricate brick-and-mortar ceramic-metal composites by using electroless plating of nickel (Ni) on alumina micro-platelets, in which Ni-coated micro-platelets are subsequently aligned by a magnetic field, taking advantage of ferromagnetic properties of Ni. The assembled Ni-coated ceramic scaffold is then sintered using spark plasma sintering (SPS) to locally create Ni mortar layers between ceramic platelets, as well as to sinter the ceramic micro-platelets. The authors report on materials and mechanical properties of the fabricated composite. The results show that this approach is promising toward development of bioinspired ceramic-metal composites.
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