Journal
ACS NANO
Volume 12, Issue 2, Pages 1096-1106Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.7b06095
Keywords
3D graphene lattices; stereolithography; 3D printing hollow polymer; tailorable manipulation; self-organization design
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Funding
- Fundamental Research Funds for the Central Universities [lzujbky-2017-k17]
- National Natural Science Foundation of China [51702142]
- Program of Introducing Talents of Discipline to Universities (111 Project) [B14044]
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It is a significant challenge to concurrently achieve scalable fabrication of graphene aerogels with three-dimensional (3D) tailorable architectures (e.g., lattice structure) and controllable manipulation of microstructures on the multiscale. Herein, we highlight 3D graphene lattices (GLs) with complex engineering architectures that were delicately designed and manufactured via 3D stereolithography printed hollow polymer template-mediated hydrothermal process coupled with freeze-drying strategies. The resulting GLs with overhang beams and columns show a 3D geometric configuration with hollow carved features at the macroscale, while the construction elements of graphene cellular on the microscale exhibit a well ordered and honeycomb-like microstructure with high porosity. These GLs demonstrate multifunctional properties with robust structure, high electrical conductivity, low thermal conductivity, and superior absorption capacitance of organic solvents. Moreover, the GLs were utilized as a subtle sensor for the fast detection of chemical agents. Aforementioned superior properties of GLs confirm that the combination of 3D tailorable manipulation and self-organization design of structures on the multiscale is an effective strategy for the scalable fabrication of advanced multifunctional graphene monoliths, suggesting their promising applications as chemical detection sensors, environmental remediation absorbers, conductive electrodes, and engineering metamaterials.
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