Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 5, Pages 4662-4671Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b16271
Keywords
core-shell nanostructure; NiMoO4 nanorods; Ni-Co-S nanosheets; bind-free; asymmetric supercapacitor device
Funding
- self-determined research funds of CCNU from the colleges' basic research and operation of MOE [CCNU17TS007]
- Key Laboratory of Analytical Chemistry for Biology and Medicine of MOE [ACBM2016003]
- Key Scientific Project of Wuhan City [2013011801010598]
- Henan Science and Technology Cooperation Project [172106000064]
- National Natural Science Foundation of China [50802032, 11275082]
- Basic Scientific Research Foundation of Central China Normal University [CCNU16A05004]
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In this work, hierarchical core-shell NiMoO4@Ni-Co-S nanorods were first successfully grown on nickel foam by a facile two-step method to fabricate a bind-free electrode. The well-aligned electrode wrapped by Ni-Co-S nanosheets displays excellent nanostructural properties and outstanding electrochemical performance, owing to the synergistic effects of both nickel molybdenum oxides and nickel cobalt sulfides. The prepared core-shell nanorods in a three-electrode cell yielded a high specific capacitance of 2.27 F cm(-2) (1892 F g(-1)) at a current density of 5 mA cm(-2) and retained 91.7% of the specific capacitance even after 6000 cycles. Their electrochemical performance was further investigated for their use as positive electrode for asymmetric supercapacitors. Notably, the energy density of the asymmetric supercapacitor device reached 2.45 mWh cm(-3) at a power density of 0.131 W cm(-3), and still retained a remarkable 80.3% of the specific capacitance after 3500 cycles. There is great potential for the electrode composed of the core-shell NiMoO4@Ni-Co-S nanorods for use in an all-solid-state asymmetric supercapacitor device.
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