4.8 Article

Metal-Oxide-Based Microjets for the Simultaneous Removal of Organic Pollutants and Heavy Metals

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 24, Pages 20478-20486

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b04353

Keywords

micromotors; photocatalytic; water purificiztio; Fenton; magnetic control; iron oxide; manganese oxide

Funding

  1. European Research Council under the European Union's Seventh Framework Program (FP7)/ERC [311529]
  2. ERC-2015-PoC/Project [713608]
  3. Spanish MINECO [CTQ2015-68879-R]
  4. European Commission under Horizon 2020's Marie Sklodowska-Curie Actions COFUND scheme [712754]
  5. Severo Ochoa Programme of the Spanish Ministry of Economy and Competitiveness [SEV-2014-0425]

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Water contamination industrial and anthropogenic activities is nowadays a major issue in many countries worldwide, To address this problem, efficient water treatment technologies are required. Recent efforts have focused on the development of self-propelled micromotors that provide enhanced micromixing and mass transfer by the transportation of reactive species, resulting in higher decontamination rates, However, a real application of these micromotors is still limited due to the high cost associated to their fabrication process. Here, we present Fe2O3-decorated SiO2/MnO2 Microjets for the simultaneous removal of industrial organic pollutants and heavy metals present in wastewater. These microjets were synthesized by low-cost and scalable methods. They exhibit an average speed of 485 +/- 32 mu m s(-1) (similar to 28 body length per s) at 7% H2O2, which is the highest reported for MnO2-based tubular micrornotors. Furthermore, the photocatalytic and adsorbent properties of the microjets enable the efficient degradation of organic pollutants, such as tetracycline and rhodamine B under visible light irradiation, as well as the removal of heavy metal ions, such as Cd2+ and Pb2+.

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