Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 3, Pages 2628-2636Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b17306
Keywords
metal-organic framework; azide-alkyne cycloaddition; resorcin[4]arene; polyoxometalate; copper(I)
Funding
- National Natural Science Foundation of China [21471029, 21371030]
- Science Foundation of Jilin Province [20150623024TC-19]
Ask authors/readers for more resources
A new highly stable copper(I)-based metal-organic framework (MOF), namely, [Cu-4(I)(SiW12O40)(L)]center dot 6H(2)O-2DMF (1), was synthesized by incorporating Keggin-type polyoxometalate (POM) anions and a functionalized wheel-like resorcin[4]arene-based ligand (L) under sovothermal condition. 1 exhibits a charming 3D supramolecular architecture sandwiched by the POM anions. Noticeably, 1 has exceptional chemical stability, especially in organic solvents or aqueous solutions with a wide range of pH values. Considering the catalytically active Cu(I) sites in 1, the azide-alkyne cycloaddition (AAC) reaction was studied by employing 1 as the heterogeneous catalyst. Most strikingly, 1 exhibits excellent catalytic activity as well as recyclability for the AAC reaction.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available