Journal
CHINESE JOURNAL OF CATALYSIS
Volume 37, Issue 8, Pages 1423-1430Publisher
SCIENCE PRESS
DOI: 10.1016/S1872-2067(16)62491-9
Keywords
Cobalt(III) catalyst; Carbon-hydrogen activation; N-sulfinyl imine; Isoquinoline
Funding
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- National Natural Science Foundation of China [21272231]
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A redox-neutral avenue to access isoquinolines has been realized by a Co(III)-catalyzed C-H activation process. Starting from readily available N-sulfinyl imine substrates and alkynes, the reaction occurred via N-S cleavage with broad substrate scope and functional group compatibility in the presence of cost-effective cobalt catalysts. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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