Journal
JOURNAL OF WATER PROCESS ENGINEERING
Volume 13, Issue -, Pages 100-106Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jwpe.2016.08.009
Keywords
Anaerobic reactor; Ethanol; Long-term operation; Polyurethane foam; Sulfate
Funding
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) of Brazil
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This work evaluates the long-term performance (888 days) of a horizontal-flow anaerobic immobilized biomass (HAIB) reactor fed with synthetic wastewater containing organic matter and sulfate. The HAIB reactor achieved stable performance, exhibiting high sulfate and organic matter removal efficiencies subjected to organic matter concentration (expressed as chemical oxygen demand - COD) of 1500 mg/L and sulfate of 500 mg/L. Sulfate removal efficiency close to 100% was obtained for COD/sulfate ratios equal to or higher than 2.6, decreasing to similar to 80% for COD/sulfate ratio of 1.4. Sulfidogenesis was clearly dependent on the availability of electron donor; but not methanogenesis. The smaller COD removal efficiencies (similar to 93%) were observed at the higher sulfate (1980mg/L) and organic matter (COD of 7000mg/L) concentrations, with COD/sulfate ratio of 3.5. Under these conditions, the presence of volatile fatty acids in the effluent indicates the occurrence of methanogenesis inhibition probably due to sulfide. The fixed-film HAIB reactor did not present bed clogging throughout the entire long-term operation period, thereby leading the way to new perspectives to use the efficient treatment of sulfate-rich wastewater. (C) 2016 Published by Elsevier Ltd.
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