Journal
CHEMCATCHEM
Volume 8, Issue 19, Pages 3064-3073Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201600828
Keywords
green chemistry; nanostructures; nitrides; photochemistry; semiconductors
Categories
Funding
- Public Projects of Zhejiang Province [2014C31026, 2014C31012]
- Key Laboratory of Inorganic Functional Materials and Devices at Chinese Academy of Sciences [KLIFMD-2015-08]
- Technology Foundation for Selected Overseas Chinese Scholar of Zhejiang Province
- National Natural Science Foundation of China [51402219]
- Zhejiang Provincial Natural Science Foundation of China [LR15F050003]
Ask authors/readers for more resources
Semiconductor photocatalysis may be a promising strategy to face energy and environmental issues because it utilizes the solar energy as energy source. The artificially Z-scheme photocatalytic system has attracted special interests owing to its high efficiency and strong redox ability. Graphitic carbon nitride nanosheets (g-C3N4 NSs) display prominent performances, which are intensively investigated. Herein, we constructed an all-solid-state Z-scheme photocatalytic system and firstly immobilized g-C3N4 nanosheets on TiO2 nanotube arrays (TNTAs) by a simple method. The microstructures of prepared g-C3N4 NSs/TNTAs photocatalyst were characterized by XRD, X-ray photoelectron spectroscopy, SEM and TEM. The features of light absorption, charge separation, and charge transfer were analyzed by UV/Vis diffuse reflectance techniques, photoluminescence spectroscopy, electrochemical atomic force microscopy, and photocurrent measurement. The synthesized g-C3N4 NSs/TNTAs samples shows enhanced photocatalytic efficiency for rhodamine B degradation under visible light, which is four times more than that of pure TNTAs. Tetracycline hydrochloride could also be effectively degraded under visible light, which contributes to reducing antibiotic residues in wastewater. Additionally, g-C3N4 NSs/TNTAs also possess other advantages such as well long-term stability and easily recyclable properties. A reaction mechanism is also proposed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available