Continental igneous rock composition: A major control of past global chemical weathering

The composition of igneous rocks in the continental crust has changed throughout Earth's history. However, the impact of these compositional variations on chemical weathering, and by extension on seawater and atmosphere evolution, is largely unknown. Weuse the strontiumisotope ratio in seawater [(Sr-87/Sr-86)(seawater)] as a proxy for chemical weathering, and we test the sensitivity of (Sr-87/Sr-86)(seawater) variations to the strontium isotopic composition (Sr-87/Sr-86) in igneous rocks generated through time. We demonstrate that the Sr-87/Sr-86 ratio in igneous rocks is correlated to the epsilon hafnium (epsilon Hf) of their hosted zircon grains, and we use the detrital zircon record to reconstruct the evolution of the Sr-87/Sr-86 ratio in zircon-bearing igneous rocks. The reconstructed Sr-87/Sr-86 variations in igneous rocks are strongly correlated with the (Sr-87/Sr-86)(seawater) variations over the last 1000 million years, suggesting a direct control of the isotopic composition of silicic magmatism on (Sr-87/Sr-86)(seawate)r variations. The correlation decreases during several time periods, likely reflecting changes in the chemical weathering rate associated with paleogeographic, climatic, or tectonic events. We argue that for most of the last 1000 million years, the (Sr-87/Sr-86)(seawater) variations are responding to changes in the isotopic composition of silicic magmatism rather than to changes in the global chemical weathering rate. We conclude that the (Sr-87/Sr-86)(seawater) variations are of limited utility to reconstruct changes in the global chemical weathering rate in deep times.