Journal
CHEMISTRYSELECT
Volume 2, Issue 17, Pages 4686-4690Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201700765
Keywords
homogeneous catalysis; mild conditions; regeneration; sustainable chemistry; V-containing heteropoly acids
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Funding
- [V.44.2.4]
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At present, the aqueous solutions of low-vanadium Mo-V-phosphoric heteropoly acids (HPA-1 and HPA-2) are widely used in various areas of catalysis owing to their oxidizing ability. It has been shown that in the presence of concentrated acetic acid the reduced solutions of these HPAs can be almost completely oxidized with oxygen at high reaction rate at a temperature below 100 degrees C and atmospheric pressure. This opens broad prospects for the development of new catalytic oxidation technologies in the presence of low-vanadium heteropoly acid solutions as reversible oxidants.
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