4.6 Article

Single Walled Carbon Nanotube Based Air Pocket Encapsulated Ultraviolet Sensor

Journal

ACS SENSORS
Volume 2, Issue 11, Pages 1679-1683

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssensors.7b00585

Keywords

carbon nanotubes; UV sensor; air pocket; fast recovery; baseline drift

Funding

  1. Advanced Exploration Systems (AES) Office of the NASA HEOMD

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Carbon nanotube (CNT) is a promising candidate as a sensor material for the sensitive detection of gases/vapors, biomarkers, and even some radiation, as all these external variables affect the resistance and other properties of nanotubes, which forms the basis for sensing. Ultraviolet (UV) radiation does not impact the nanotube properties given the substantial mismatch of bandgaps and therefore, CNTs have never been considered for UV sensing, unlike the popular ZnO and other oxide nanwires. It is well-known that UV assists the adsorption/desorption characteristics of oxygen on carbon nanotubes, which changes the nanotube resistance. Here, we demonstrate a novel sensor structure encapsulated with an air pocket, where the confined air is responsible for the UV sensing mechanism and assures sensor stability and repeatability over time. In addition to the protection from any contamination, the air pocket encapsulated sensor offers negligible baseline drift and fast recovery compared to previously reported sensors. The air pocket isolated from the outside environment can act as a stationary oxygen reservoir, resulting in consistent sensor characteristics. Furthermore, this sensor can be used even in liquid environments.

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