4.6 Article

Severe Morphological Deformation of Spiro-OMeTAD in (CH3NH3)Pbl3 Solar Cells at High Temperature

Journal

ACS ENERGY LETTERS
Volume 2, Issue 8, Pages 1760-1761

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.7b00582

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Funding

  1. Japan Science and Technology Agency-Advanced Low Carbon Technology R&D program (ALCA)
  2. New Energy and Industrial Technology Development Organization (NEDO)
  3. Japanese Society for Promotion of Science (JSPS)

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The hole transport material, spiro-OMeTAD, in MAPbI(3) perovskite solar cells undergoes severe morphological deformation at high temperature, showing big voids in the layer when the devices are heated at 80 degrees C and above. It is puzzling that the voids emerge only in the area where the spiro-OMeTAD is capped with Au film and only in the case where the HTM contains both LiTFSI and TBP as additives.

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