Journal
ACS ENERGY LETTERS
Volume 2, Issue 9, Pages 2183-2186Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.7b00707
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Funding
- seventh European Community Framework Programme [614897]
- framework programme for research and Innovation Horizon under the Marie Sklodowska-Curie [691185]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-ACO2-05CH11231]
- Marie Curie Actions (MSCA) [691185] Funding Source: Marie Curie Actions (MSCA)
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CsPbI3 nanocrystals are still limited in their use because of their phase instability as they degrade into the yellow nonemitting delta-CsPbI3 phase within a few days. We show that alloyed CsPbxMN1-x,I-3 nanocrystals have essentially the same optical features and crystal structure as the parent a-CsPbI3 system, but they are stable in films and in solution for periods over a month. The stabilization stems from a small decrease in the lattice parameters slightly increasing the Goldsmith tolerance factor, combined with an increase in the cohesive energy. Finally, hybrid density functional calculations confirm that the Mn2+ levels fall within the conduction band, thus not strongly altering the optical properties.
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