Journal
SCIENCE CHINA-MATERIALS
Volume 60, Issue 12, Pages 1179-1186Publisher
SCIENCE PRESS
DOI: 10.1007/s40843-017-9120-6
Keywords
cobalt phosphide nanowire; hydrogen evolution reaction; supercapacitor
Categories
Funding
- National Natural Science Foundation of China [51732010, 51571172, 11404280, 51672240, 51571171]
- Natural Science Foundation for Distinguished Young Scholars of Hebei Province [E2017203095]
- Natural Science Foundation of Hebei Province [E2016203484, A2015203337]
- Research Program of the College Science AMP
- Technology of Hebei Province [ZD2017083, QN2014047]
- Graduate Innovation Fund [CXZZSS2017055, 2017XJSS044]
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In this paper, we report CoP nanowires supported on carbon cloth (CC) (CoP/CC) as a bifunctional electrode for hydrogen evolution reaction (HER) and supercapacitor. CoP/CC possess an excellent electrocatalytic performance for HER, with a Tafel slope of 56 mV/dec and a low overpotential of 68 mV to achieve a current density of 10 mA cm(-2). Remarkably, the bifunctional CoP/CC used as electrode for supercapacitor exhibit a higher specific capacitance of 674 F g(-1) at a scan rate of 5 mV s(-1) and maintains long-life cycling stability, retaining 86% of the initial capacitance after 10,000 cycles. CoP/CC will be a promising candidate as electrode for HER and supercapacitor.
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