4.7 Article

Low thermal-conductivity and high thermal stable silica aerogel based on MTMS/Water-glass co-precursor prepared by freeze drying

Journal

MATERIALS & DESIGN
Volume 113, Issue -, Pages 246-253

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2016.09.083

Keywords

Silica aerogels; MTMS/Water-glass; Freeze drying; Hydrophobic; Thermal stability

Funding

  1. Anhui Programs for Science and Technology Development [1604a0902175]
  2. Fundamental Research Funds for the Central Universities [WK2320000032]

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In this paper, hybrid silica aerogels were prepared by methltrimethoxysilane (MTMS) and water-glass co-precursor through two-step sol-gel process followed by freeze drying (FD). The characteristics of aerogels were strongly affected by the molar ratio of MTMS/Water-glass. When the molar ratio is 5.1, hybrid aerogel was obtained with good performances, such as low density (0.083 g/cm(3)), high contact angle (155.1 degrees) and low thermal conductivity (0.0226 W/m.K). The density, contact angle and thermal conductivity of aerogels based on co-precursor are still showing excellent thermal stability with the same performances after 550 degrees C heat-treatment. (C) 2016 Published by Elsevier Ltd.

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