4.7 Article

Rechargeable Sodium All-Solid-State Battery

Journal

ACS CENTRAL SCIENCE
Volume 3, Issue 1, Pages 52-57

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acscentsci.6b00321

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Funding

  1. National Science Foundation [CBET-1438007]
  2. U.S. Department of Materials Science and Engineering [DOE-SC0005397]
  3. Div Of Chem, Bioeng, Env, & Transp Sys
  4. Directorate For Engineering [1438007] Funding Source: National Science Foundation

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A reversible plating/stripping of a dendrite-free metallic-sodium anode with a reduced anode/ceramic interfacial resistance is created by a thin interfacial interlayer formed in situ or by the introduction of a dry polymer film. Wetting of the sodium on the interfacial interlayer suppresses dendrite formation and growth at different discharge/charge C-rates. All-solid-state batteries were obtained with a high cycling stability and Coulombic efficiency at 65 degrees C.

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