Journal
ACS CENTRAL SCIENCE
Volume 3, Issue 7, Pages 692-700Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscentsci.7b00212
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Funding
- National Institutes of Health (National Institute of General Medical Sciences) [R01GM062871, R01-GM109194]
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Classical methods for achieving nucleophilic substitutions of alkyl electrophiles (S(N)1 and S(N)2) have limited scope and are not generally amenable to enantioselective variants that employ readily available racemic electrophiles. Radical-based pathways catalyzed by chiral transition-metal complexes provide an attractive approach to addressing these limitations.
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