Journal
SCIENCE BULLETIN
Volume 62, Issue 17, Pages 1201-1206Publisher
SCIENCE PRESS
DOI: 10.1016/j.scib.2017.08.020
Keywords
Gold; Heterocycles; Migration; Cyclization; Tandem reaction
Categories
Funding
- National Natural Science Foundation of China [21622204, 21572186]
- Natural Science Foundation of Fujian Province [2015J06003]
- Xiamen University [20720150045]
- NFFTBS [J1310024]
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A gold-catalyzed intermolecular reaction of ynamides with 3-indolyl azides via the presumable a-imino gold carbenes has been developed, providing an alternative and efficient way for the synthesis of valuable 3-amino-b-carbolines in generally good to excellent yields. Importantly, this new protocol involves an unexpected 1,2-alkyl migration pathway. (C) 2017 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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