Journal
RSC ADVANCES
Volume 6, Issue 97, Pages 94365-94372Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra21196h
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Funding
- Fundamental Research Funds for the Central Universities [Izujbky-2014-72]
- National Natural Science Foundation of China [51103168, 21201093]
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A series of covalent triazine frameworks containing Troger's base segments (CTF-TBs) were designed and prepared by dynamic trimerization under ionothermal conditions, based on the novel dicyano monomer of dicyano Troger's base (DCTB). The CTF-TBs were all amorphous and exhibited surface areas between 294 to 732 m(2) g(-1). The effect of reaction conditions including ratio of catalyst/monomer and temperature on the pore properties was discussed. Meanwhile, the adsorption capacity of CO2 for all the CTF-TBs was studied and the CO2 uptake capacity was up to 16.84 wt% at 273 K and 1.10 bar for CTF-TB-3.
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