Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 4, Issue 2, Pages 271-276Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00597g
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Funding
- Ministry of Science of Technology of China [2016YFA0202900]
- NSFC [21232009, 20421091]
- CAS [QYZDY-SSW-SLH012]
- Science and Technology Commission of Shanghai Municipality
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Spiroketal backbone based diphosphine ligands (SKP) were disclosed to be highly efficient and enantioselective (94 ->.99% ee) in the palladium catalyzed asymmetric allylic amination of 2-diethylphosphonate- substituted allylic acetates, affording a series of chiral beta- aminophosphonates bearing an alpha- methylene functionality in high yields with excellent regioselectivities.
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