Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 4, Issue 10, Pages 1958-1961Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00450h
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Funding
- National Key Research and Development Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21421062, 21522205, 21672110]
- State Key Laboratory of Elemento-Organic Chemistry
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The first example of a silver-mediated fluorination of alkyl iodides with the Ruppert-Prakash reagent (TMSCF3) as a fluorinating agent has been reported. This reaction is compatible with a variety of functional groups and proceeds under mild reaction conditions. Moreover, we demonstrate that the large surface area of CaF2 dramatically increased the reaction yield.
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