Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 4, Issue 8, Pages 1528-1532Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00211d
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Funding
- Department of Science & Technology of Jilin Province [20170414052GH]
- National Natural Science Foundation of China (NSFC) [51573069]
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The first nickel-catalyzed C-H selective fluorination of 8-aminoquinoline derivatives at the C-5 position was achieved using NFSI (N-fluorobenzenesulfonimide) as the F source and NiSO4 as the catalyst. This method demonstrated broad substrate tolerance under mild conditions and a plausible SET (single electron transfer) mechanism was suggested in the proposal of a radical process.
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