Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 4, Issue 9, Pages 1833-1838Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00405b
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Funding
- National Natural Science Foundation of China [21372219]
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A silver-catalyzed intermolecular tandem cyclization of nitrones with 2-azetine was developed for the synthesis of 2,3-disubstituted quinolines under mild conditions with good yields. This approach features a C-N bond cleavage of 2-azetine and an N-O bond cleavage of nitrones via a radical pathway. The results of this study provide a new reaction pattern for nitrones and may find applications in the synthesis of other heterocycles.
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