Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 4, Issue 2, Pages 234-240Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qi00526h
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Funding
- National Science Foundation of China [21301148, 21671102]
- National Science Foundation of Jiangsu Province [BK20161538]
- Innovative Research Team Program by the Ministry of Education of China [IRT13070]
- State Key Laboratory of Coordination Chemistry [SKLCC1616]
- State Key Laboratory of Materials- Oriented Chemical Engineering [ZK201406]
- Six talent peaks project in Jiangsu Province [JY-030]
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A new zeolitic-like microporous coordination polymer (PCP), [Zn-2(L) center dot 2H(2)O].guest (named NTU-17), with crb (BCT) topology was designed and prepared. Interestingly and unusually, it is the first time that such rod-shaped NTU-17 crystals could be converted to morphology-preserved carbon rods with exclusive micropores and a large surface area by using a facile method of direct thermal transformation. Gas adsorption and selectivity showed that these PCP dependent carbon rods are suitable solid adsorbents for CH4 purification.
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