Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 4, Issue 4, Pages 727-735Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qi00047b
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Funding
- National Natural Science Foundation of China [21671205, U1407103]
- Collaborative Innovation Centre of Henan Textile and Clothing Industry, Innovation Scientists and Technicians Troop Construction Projects of Henan Province [164100510007, CXTD2015018]
- Zhengzhou University [1421316035, 2016xjxm258]
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A series of hierarchical nanoarrays with a lavender-like structure was synthesized via a facile in situ hydrothermal method by sequential partial ion exchange. Hierarchical Ni@Ni3S2 nanoarrays that were partially surrounded with nanoflakes were first fabricated by simultaneously using Ni foam as a template and as a source. The hierarchical structure was composed of one-dimensional rods combined with two-dimensional nanoflakes. Furthermore, Co and Se ions, as the beneficial cation and anion, were successfully introduced into the hierarchical Ni@Ni3S2 material by sequential partial ion exchange. This reaction formed Ni@Ni3S2/Co9S8 and Ni@Ni3S2/Co9S8/NiSe composite multilevel electrodes with structures that were similar to those of the parent materials. All the as-prepared materials were assembled into asymmetric supercapacitor devices to explore their electrochemical performance. Compared with single-component Ni@Ni3S2, the Ni@Ni3S2/Co9S8/NiSe//active carbon device exhibited a better rate performance of 78.93 F g(-1) at a current density of 1 A g(-1) (retaining 75% from 1 A g(-1) to 10 A g(-1)). This device still delivered an energy density of 17.75 Wh kg(-1) even at a high power density of 1945.2 W kg(-1). This finding demonstrated that Ni@Ni3S2/Co9S8/NiSe is a promising electrode material for supercapacitors.
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