Journal
ADVANCED ELECTRONIC MATERIALS
Volume 3, Issue 7, Pages -Publisher
WILEY
DOI: 10.1002/aelm.201700097
Keywords
air-stable semiconductors; charge-transfer complexes; organic thin-film transistors; printed electronics; solution shearing
Funding
- Nippon Kayaku Co., Ltd. under the approval of the Photon Factory Program Advisory Committee [2014S2-001]
- JSPS KAKENHI [JP16H05976, JP26246014]
- Grants-in-Aid for Scientific Research [17H05144, 26246014] Funding Source: KAKEN
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Thin-film formation by solution-shearing technique is examined for layered-crystalline donor-acceptor charge-transfer compounds composed of 2,7-dioctyl[1] benzothieno[3,2-b][ 1] benzothiophene as a donor and optionally fluorinated derivatives of tetracyanoquinodimethane (n = 0, 2, 4) as acceptors. Polycrystalline thin films of the compounds whose crystalline size is over 2 mm along the blade-scan axis are successfully fabricated, and the formed films demonstrate anisotropic alignment of the crystalline grains where the crystal a-axis with the largest transfer integral is parallel to the blade-scan axis. Such anisotropic alignment of large crystalline grains affords air-stable n-type field-effect operation with a mobility as high as 0.61 cm(2) V-1 s(-1) which is comparable to that of the single-crystal devices.
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