4.1 Article

Empirical Lewis acid strengths for 135 cations bonded to oxygen

Publisher

INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2052520617010988

Keywords

Lewis acidity; valence-matching principle; bond valence; ionization energy; electronegativity

Funding

  1. Natural Sciences and Engineering Research Council of Canada
  2. University of Manitoba

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New and updated Lewis acid strengths are listed for 135 cations bonded to oxygen for use with published Lewis base strengths. A strong correlation between Lewis acid strength and ionization energy is shown, and correlation with electronegativity is confirmed.

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