Journal
JOURNAL OF CHEMICAL SCIENCES
Volume 128, Issue 12, Pages 1849-1853Publisher
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-016-1191-0
Keywords
Aminonitrile; monohydrocyanation; diamine; potassium hexacyanoferrate(II)
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Funding
- National Natural Science Foundation of China [21462038, 21362034]
- Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education
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The selective monohydrocyanation of diimines using potassium hexacyanoferrate(II)-benzoyl chloride reagent system as a cyanide source under catalyst-free condition is described. The advantages of this protocol are the non-toxic, non-volatile and inexpensive cyanide source, high yield, and simple work-up procedure.
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