4.7 Article

Method of moments: A versatile tool for deterministic modeling of polymerization kinetics

Journal

EUROPEAN POLYMER JOURNAL
Volume 68, Issue -, Pages 139-160

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2015.04.018

Keywords

Method of moments; Modeling; Polymer molecular weight; Polydispersity index; Polymerization kinetics; Polymer modification

Funding

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)

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Method of moments is a simple deterministic method widely applicable in modeling various polymerization processes. This method is easy to use and computationally inexpensive. Although the mathematics involved is simple and elementary, the derivation step is often lengthy and thus it may be intimidating. This paper aims to serve as a tutorial by providing step-by-step guide on how to apply the method of moments to different polymerization and polymer modification systems. The basics behind method of moments, the limitation related to it, and common problems encountered in derivation with ways to counter them are described in details. Several examples are presented to clearly elucidate these concepts. Crown Copyright (C) 2015 Published by Elsevier Ltd. All rights reserved.

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