Journal
NANO-MICRO LETTERS
Volume 10, Issue 1, Pages -Publisher
SHANGHAI JIAO TONG UNIV PRESS
DOI: 10.1007/s40820-017-0164-2
Keywords
NiCo2O4; Double-shelled hollow sphere; Microwave; Sodium ion battery
Funding
- Science Foundation of Sichuan Province [2016FZ0070]
- Natural Science Foundation of China (NSFC) [201476145]
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The ternary transitional metal oxide NiCo2O4 is a promising anode material for sodium ion batteries due to its high theoretical capacity and superior electrical conductivity. However, its sodium storage capability is severely limited by the sluggish sodiation/desodiation reaction kinetics. Herein, NiCo2O4 double-shelled hollow spheres were synthesized via a microwave-assisted, fast solvothermal synthetic procedure in a mixture of isopropanol and glycerol, followed by annealing. Isopropanol played a vital role in the precipitation of nickel and cobalt, and the shrinkage of the glycerol quasi-emulsion under heat treatment was responsible for the formation of the double-shelled nanostructure. The as-synthesized product [GRAPHICS] was tested as an anode material in a sodium ion battery, was found to exhibit a high reversible specific capacity of 511 mAh g(-1) at 100 mA g(-1), and deliver high capacity retention after 100 cycles.
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