Journal
JOURNAL OF CO2 UTILIZATION
Volume 20, Issue -, Pages 301-311Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jcou.2017.05.021
Keywords
Hybrid photocatalyst; Z-scheme; CO2 conversion; Solar spectrum active; Nanorods; Nanoparticles
Funding
- DGIST R & D Program of the Ministry of Education, Science and Technology of Korea [17-BD-0404, 17-01-HRLA-01]
- National Research Foundation of Korea - Ministry of Science, ICT & Future Planning [2013R1A1A008678, 2014K1A3A1A47067086]
- National Research Foundation (NRF) - Ministry of Science, ICT & Future Planning [2015M1A2A2074670]
- Ministry of Science & ICT (MSIT), Republic of Korea [17-01-HRLA-01, 17-BD-0404] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2014K1A3A1A47067086] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Development of photocatalytic materials for achieving the aspects of cost-effectiveness, improved performance and high stability is a subject of enormous interest among the photocatalysis research society. With the aim of achieving above mentioned features, herein we report a noble metal free, solar-light active, efficient and highly stable hybrid Cu2ZnSnS4 (CZTS)-ZnO photocatalyst, synthesized by a simple two-step process. The morphological, crystalline, band alignment, optical and electronic properties of the prepared samples are intensively investigated. Photocatalytic performance is evaluated by measuring, under the simulated solar light, the ability of the photocatalyst to convert CO2 into hydrocarbon fuels, primarily CH4. Our optimum CZTS-ZnO photocatalyst sample exhibits a CH4 yield of 138.90 ppm g(-1) h(-1), a factor of approximate to 31 times greater than the un-sensitized ZnO nanorods, and approximate to 22 times greater than the CZTS nanoparticles; with excellent stability yielding similar CH4 production up to five test-cycles. The enhanced performance of the hybrid, noble metal-free photocatalyst can be attributed to improved light absorption and efficient separation of the photogenerated charge due to the Z-scheme heterojunction interface.
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