Journal
CHEMELECTROCHEM
Volume 4, Issue 6, Pages 1463-1469Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201700173
Keywords
silicon nanoparticles; graphitic carbon spheres; composite hollow spheres; anode materials; lithium-ion batteries
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Funding
- tional Natural Science Foundation of China [51602057, 51673041, 51322307, 51273218, 51133001, 21374018]
- Shu Guang project - Shanghai Municipal Education Commission [14SG04]
- Shu Guang project - Shanghai Education Development Foundation [14SG04]
- Shanghai talent development fund [201643]
- China Postdoctoral Science Foundation [2016 M591602]
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Silicon is known to be a promising candidate anode material for lithium-ion batteries because of its ultrahigh capacity; however, its volume expansion/shrinkage during lithiation/delithiation reactions represent the biggest challenge in practical applications. In this paper, we successfully design and synthesize a new type of robust silicon nanoparticles@void@graphitic carbon spheres (Si@void@C) material to buffer the silicon volume changes in the cyclic lithiation/delithiation process. The as-obtained Si@void@C nanocomposite spheres with well-dispersed silicon nanoparticles, efficient void spaces, and graphitic carbon shells can endow this nanocomposite anode with the robustness to solve the volume expansion/shrinkage issue. As demonstrated by coin battery performances, the Si@void@C nanocomposite sphere-based anode exhibits a specific capacity retention of 1565 and 1260 mAhg(-1) at C/5 and C/2 (1C=4200 mAg(-1)), respectively, after 1000 cycles of deep charge/discharge processes (voltage between 0.01 and 2.7 V versus Li/Li+). It provides a promising anode for a safe and high-performance Si-based materials in high-performance lithium-ion batteries.
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