Journal
CHEMELECTROCHEM
Volume 4, Issue 9, Pages 2293-2299Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201700322
Keywords
in situ fabrication; lithium battery; all solid state; poly(ethylene oxide); composite polymer electrolyte
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Funding
- National Natural Science Foundation of China [21573036, 51602048]
- Education Department of Jilin Province [111099108]
- Science Technology Program of Jilin Province [20150520027JH]
- Jilin Provincial Research Center of Advanced Energy Materials (Northeast Normal University)
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In this work, we propose an in situ hydrolytic method to synthesize SiO2 nanoparticles, which are incorporated in poly (ethylene oxide)-based polymer in the presence of lithium salt with a large anion (lithium bis(oxalate)borate). When evaluated as the solid electrolyte for electrochemical performance in lithium batteries, the as-prepared composite polymer electrolyte (CPE) exhibits an exciting ion conductivity of 1.9 mS/cm at 80 degrees C. Moreover, the CPE shows a decent Li+ transference number up to 0.69 and wide electrochemical window of 5.05 V at 60 degrees C. Furthermore, the Li/LiFePO4 cell assembled by the CPE exhibits an impressive capacity of 156.3 mAh/g at 60 degrees C under 0.05 C (1 C=160 mA/g). Considering the aspects mentioned above, the prepared CPE has the potential to be applied in practical high-temperature batteries with a long-term service life. More importantly, the synthetic strategy is favorable for enhancing both physical and electrochemical performance for solid electrolyte and may provide a new strategy for study and fabrication of lithium batteries.
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